Round robin tests XRF-analysis XRF Round-robin test GeoPT 40, England - ShWYO-1, Silty marine shale
Study organized by:
International Association of Geoanalysts and Geostandards Newsletter - GeoPT40
Material of proficiency test:
ShWYO-1, Silty marine shale
Study finished:
2017 - 2
Literature:
Report - GeoPT40 Proficiency Testing Round 40 (Laborcode CRB = W128)
major elements [wt %]
CRB | RV | 1sRV | Z-Score | |
Na₂O | 1,020 | 1,000 | 0,020 | -0,490 |
MgO | 2,830 | 2,850 | 0,049 | -0,210 |
Al₂O₃ | 13,100 | 13,130 | 0,178 | -0,090 |
SiO₂ | 61,850 | 61,870 | 0,665 | -0,020 |
P₂O5 | 0,181 | 0,181 | 0,005 | 0,010 |
S * | 0,750 | 0,680 | 0,130 | |
K₂O | 2,450 | 2,454 | 0,043 | -0,050 |
CaO | 3,930 | 3,940 | 0,064 | -0,080 |
TiO₂ | 0,570 | 0,565 | 0,012 | 0,200 |
Fe₂O₃tot | 4,670 | 4,643 | 0,074 | 0,180 |
MnO | 0,045 | 0,043 | 0,001 | 0,710 |
L.O.I. * | 7,500 | 7,770 | 0,650 | |
TC | 1,070 | 1,030 | 0,002 | 1,060 |
TOC* | 0,300 | 0,250 | 0,060 |
trace elements [µg/g]
CRB | RV | 1sRV | Z-Score | |
As | 12,00 | 11,80 | 0,60 | 0,19 |
Ba | 558,00 | 580,00 | 17,80 | -0,62 |
Ce | 55,00 | 54,50 | 2,40 | 0,11 |
Cl * | 130,00 | 96,00 | 41,00 | |
Co | 11,00 | 10,80 | 0,60 | 0,17 |
Cr | 72,00 | 68,30 | 2,90 | 0,64 |
Cs | 8,00 | 7,10 | 0,40 | 1,02 |
Cu | 24,00 | 23,50 | 1,20 | 0,20 |
F * | 420,00 | 634,00 | 133,00 | |
Ga | 17,00 | 15,70 | 0,80 | 0,76 |
Hf | 5,10 | 5,04 | 0,30 | 0,10 |
La | 29,00 | 28,40 | 1,40 | 0,21 |
Mo | 2,00 | 1,20 | 0,10 | 4,28 |
Nb | 12,00 | 11,30 | 0,60 | 0,60 |
Nd | 26,00 | 25,00 | 1,20 | 0,41 |
Ni | 31,00 | 27,80 | 1,30 | 1,19 |
Pb | 22,00 | 20,10 | 1,00 | 0,94 |
Pr | 7,00 | 6,60 | 0,40 | 0,50 |
Rb | 105,00 | 101,00 | 4,00 | 0,50 |
Sc | 13,00 | 11,50 | 0,60 | 1,22 |
Sm | 5,00 | 4,90 | 0,30 | 0,16 |
Sr | 194,00 | 195,00 | 7,00 | -0,05 |
Th | 7,00 | 9,00 | 0,50 | -1,93 |
U | 3,00 | 3,20 | 0,20 | -1,16 |
V | 117,00 | 117,00 | 4,60 | 0,00 |
Y | 24,00 | 23,10 | 1,20 | 0,39 |
Zn | 100,00 | 97,00 | 3,90 | 0,38 |
Zr | 184,00 | 183,00 | 6,70 | 0,07 |
Legend
CRB
results CRB
cooperative test
results collaborative study
1s-RV
Standard deviation collaborative study
Z-Score
Difference of measured value from mean study
*
Value not certified